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General information on air conditioning systems -> Principles of air conditioning systems for Your Audi A2 SUV 1999-2005

Audi 100 1991 ➤ , Audi 80 1992 ➤ , Audi A1 2011 ➤ , Audi A1 Sportback 2 ...  
Air conditioner with refrigerant R134a - Edition 11.2018  
⇒ “1 Warning instructions when working on vehicles with high-  
voltage system”, page 1 .  
2.5  
Principles of air conditioning systems  
⇒ “2.5.1 Physical principles”, page 7  
⇒ “2.5.2 Pressure and boiling point”, page 7  
⇒ “2.5.3 Vapour pressure table for refrigerant R134a”,  
page 8  
⇒ “2.7 Properties of refrigerant R134a”, page 11  
2.5.1  
Physical principles  
The four familiar states of water apply to air conditioning refriger‐  
ants, too.  
1 - Gas (invisible)  
2 - Vapour  
3 - Liquid  
4 - Solid  
When water is heated in a vessel (heat absorption), water vapour  
can be seen to rise. If the vapour is further heated through heat  
absorption, the visible vapour turns into invisible gas. The process  
is reversible. If heat is extracted from gaseous water -A-, it  
changes first to vapour -B-, then to water and finally to ice.  
A - Heat absorption  
B - Heat emission  
Heat always flows from a warmer to a colder substance  
Every substance consists of a mass of moving molecules. The  
fast-moving molecules of a warmer substance give off some of  
their energy to the cooler and thus slower molecules. As a result,  
the molecular motion of the warmer substance slows down and  
that of the colder substance is accelerated. This process contin‐  
ues until the molecules of both substances are moving at the  
same speed. They are then at the same temperature and no fur‐  
ther heat exchange takes place.  
2.5.2  
Pressure and boiling point  
The boiling point given in tables for a liquid is always referenced  
to an atmospheric pressure of 1 bar. If the pressure acting on a  
liquid changes, its boiling point also changes.  
2. General information on air conditioning systems  
7
Audi 100 1991 ➤ , Audi 80 1992 ➤ , Audi A1 2011 ➤ , Audi A1 Sportback 2 ...  
Air conditioner with refrigerant R134a - Edition 11.2018  
Note  
Pressure can be measured in various units: 1 MPa (megapascal)  
is equivalent to 10 bar gauge pressure, or 145 psi; 1 bar absolute  
pressure is the same as 0 bar gauge pressure, which is roughly  
equivalent to atmospheric pressure.  
For example, water boils at a lower temperature the lower the  
pressure.  
The vapour pressure curves for water and refrigerant R134a  
show, for example, that, at constant pressure, reducing the tem‐  
perature changes vapour to liquid (in the condenser) or that, for  
instance, reducing the pressure causes the refrigerant to change  
from liquid to vapour (in the evaporator).  
Vapour pressure curve for water  
A - Liquid  
B - Gaseous  
C - Vapour pressure curve for water  
1 - Pressure acting on liquid in bar (absolute)  
2 - Temperature in °C  
Vapour pressure curve for refrigerant R134a  
A - Liquid  
B - Gaseous  
D - Vapour pressure curve for refrigerant R134a  
1 - Pressure acting on liquid in bar (absolute)  
2 - Temperature in °C  
2.5.3  
Vapour pressure table for refrigerant  
R134a  
The vapour pressure table for every refrigerant is published in the  
literature for refrigeration system engineers. This table makes it  
possible to determine the vapour pressure acting on the column  
of liquid in a vessel if the temperature of the vessel is known.  
As there is a characteristic vapour pressure table for every refrig‐  
erant, it is possible to identify the type of refrigerant by measuring  
pressure and temperature.  
8
Rep. gr.87 - Air conditioning system